Now showing items 81-100 of 141
Torres Antón, Òscar (Date of defense: 2017-02-24)
Some of the most powerful methods for synthesizing complex organic molecules with high levels of chemo-, diastereo- and enantioselectivity rely on metal carbene chemistry. These compounds are versatile reaction intermediates ...
Rich Masallera, Jordi (Date of defense: 2012-06-08)
The catalytic asymmetric oxidation of alkenes has special interest from both industrial and academic points of view. For this reason, catalysts able to perform these reactions in a faster and more effective manner have ...
Sens Llorca, Cristina (Date of defense: 2005-03-17)
Se han sintetizado dos nuevos complejos mononucleares de Ru, con formula [RuCl2(Hbpp)(dmso)2], a partir de la reacción entre [RuCl2(dmso)4] y Hbpp (3,5-bis(2-piridil)pirazola). El hecho que sólo tres de los seis posibles ...
Sala Román, Xavier (Date of defense: 2007-03-16)
Síntesi de nous complexos de Ruteni amb lligands no quirals que tenen per fórmula [Ru(phen)([9]aneS3)X] (on X = H2O, py i MeCN). Caracterització espectroscòpica electroquímica i estructural d'aquesta família de complexos. ...
Masllorens i Llinàs, Judit (Date of defense: 2006-02-10)
Aquesta Tesi Doctoral està dividida en diferents capítols tots ells basats en aplicacions de macrocicles nitrogenats triolefínics de 15 membres i dels seus complexos amb metalls de transició. En primer lloc es descriu ...
Mola i Marín, Joaquim (Date of defense: 2008-06-27)
La Tesi descriu de manera completa una sèrie de complexos de ruteni amb lligands polipiridílics i lligands auxiliars de tipus fosfina, dmso, nitril o aquo. Es descriuen estudis d'isomerització (cis/trans o coordinació ...
Vieta i Corcoy, Pep Anton (Date of defense: 2017-02-07)
Throughout this thesis I was involved in different science communication projects where research and innovation have been applied to improve existing proposals and exploring new formats without forget the evaluation of the ...
Turull López, Marta (Date of defense: 2019-07-19)
This thesis is focused on the use of the Diffusive Gradient in thin film (DGT) technique for the analysis of bioavailable mercury and other trace metals in water and soil. Homemade DGT devices using a selective ion-exchange ...
Nadal i Soy, Josep (Date of defense: 2002-12-10)
Els polímers són una sèrie de compostos que troben un ampli ventall d'aplicacions en la indústria actual. Un exemple són les espumes de poliuretà, estructures de tipus cel·lular obtingudes mitjançant la reacció química ...
Company Casadevall, Anna (Date of defense: 2008-12-16)
L'activació d'oxigen que té lloc en els éssers vius constitueix una font d'inspiració pel desenvolupament d'alternatives als oxidants tradicionals, considerats altament tòxics i nocius. En aquesta treball s'utilitzen ...
Torrent Fàbrega, Laura (Date of defense: 2019-10-09)
The production of engineered nanomaterials (ENMs) has grown in last years due to their special physicochemical properties in respect to their bulk counterparts, derived from their small size (1-100 nm). Among the existing ...
El Hamdi Lahfid, Majid (Date of defense: 2013-10-15)
Structural isomers are molecules that have the same number and type of atoms but arranged in different manner. The isomerization energy is the energy difference between two isomers, i.e. the energy cost corresponding to ...
Milan, Michela (Date of defense: 2018-10-30)
The oxidation of aliphatic C-H bonds is a very powerful reaction because it allows the functionalization of inert C-H bonds, converting them into a suitable sites for further chemical elaboration. It also represents one ...
Soler Vives, Marta (Date of defense: 2015-02-02)
Nowadays, the search for new drugs against cancer is one of the major goals to improve the quality of life of patients. The development of more selective treatments against cancer cells may lead to a significant reduction ...
Afonso Afonso, Ana (Date of defense: 2011-07-22)
En aquesta tesi doctoral es va estudiar la preparació de pèptids biarílics en fase sòlida. En primer lloc, es varen borilar residus de fenilalanina o tirosina presents a la seqüència peptídica a través d’una reacció de ...
Majumder, Santanu (Date of defense: 2013-10-30)
Apart from the geological controls that can cause As mobilization in groundwater in the Bengal Delta Plain, local anthropogenic factors may also contribute to some extent. Investigations showed that As(III) get enriched ...
Masllorens i Llinàs, Ester (Date of defense: 2006-03-10)
Aquesta tesi doctoral es basa en l'estudi de l'aplicació en catàlisi de dos tipus de complexos organometallics basats en dos metalls de tansició diferents. Concretament s'estudien complexos macrocíclics triolefínics de ...
Clarasó Petit, Carlota (Date of defense: 2019-02-08)
Metalloenzymes are a fundamental source of inspiration for synthetic chemists. Oxidation metalloenzymes catalyze oxidation reactions with high efficiency under very mild experimental conditions exhibiting exquisite regio- ...
Garcia López, Lídia (Date of defense: 2012-02-24)
The development of new chemical processes and efficient catalysts for the formation of carbon-carbon bonds is an important topic in organic chemistry. In particular, the [2+2+2] cycloaddition reaction involving different ...
Rovira Coll, Mireia (Date of defense: 2017-03-10)
Organometallic aryl-CuIII species have been proposed as key intermediates in Ullmann-type reactions. However, such species have long remained elusive and mechanistic investigations of a plausible catalytic cycle remained ...