2024-03-28T19:09:24Zhttps://www.tdx.cat/oai/requestoai:www.tdx.cat:10803/4043062021-03-16T11:10:19Zcom_10803_480col_10803_386424
TDX (Tesis Doctorals en Xarxa)
author
Mejuto Nieblas, Carmen
authoremail
mejuto@uji.es
authoremailshow
false
director
Peris Fajarnés, Eduardo
director
Guisado Barrios, Gregorio
authorsendemail
true
2017-07-03T14:41:57Z
2017-07-03T14:41:57Z
2017-06-16
http://hdl.handle.net/10803/404306
http://dx.doi.org/10.6035/14002.2017.532357
In summary, a series of polytopic ligands based on NHC and MIC ligands have been synthesized in this Doctoral Thesis by means of different synthetic routes that gave rise to systems with very sophisticated architectures. A large variety of metal complexes have been formed based on these salt precursors that allowed the preparation of homo and heteroleptic mono-, di- and tri-metal complexes with different geometries. The luminescence properties of various imidazolium salts, the catalytic activity of some of the metal complexes obtained, and host-guest molecular recognition studies have been analyzed.En esta Tesis Doctoral se ha sintetizado una serie de ligandos politópicos basados en ligandos NHC y MIC mediante diferentes rutas sintéticas que dieron lugar a sistemas con arquitecturas muy sofisticadas. Se ha procedido a la formación de una gran variedad de complejos metálicos basados en dichas sales precursoras que permitieron la obtención de complejos mono-, di- y tri-metálicos homo y heterolépticos con diferentes geometrías. Se han analizado las propiedades luminiscentes de varias sales de imidazolio, la actividad catalítica de algunos de los complejos metálicos obtenidos y se han llevado a cabo estudios de reconocimiento molecular host-guest.
eng
N-Heterocyclic Carbene Ligands
Self-Assembly
Host-Guest Chemistry
Mesoionic Carbene Ligands
Catalysis
Polyaromatic
Poly-N-Heterocyclic Carbene Ligands with Polyaromatic Linkers. Self-Assembly and Host-Guest Chemistry
info:eu-repo/semantics/doctoralThesis info:eu-repo/semantics/publishedVersion
URL
https://www.tdx.cat/bitstream/10803/404306/1/2017_Tesis_Mejuto%20Nieblas_Carmen.pdf
File
MD5
b8ddffbb063e886dc79fe2558355c175
11980058
application/pdf
2017_Tesis_Mejuto Nieblas_Carmen.pdf